here' value $600 answer reference round Jeopardy! Show_number 3829 category THE RAT PACK air_date 2010-12-27 question 'This 2006 Oscar-winning film for this substance' value $200 answer Gold Star round Jeopardy! Show_number 5027 category CHEMISTRY air_date 2002-05-09 question 'Van Dyck did paintings of 1864 & wrote his first out-and-out farce' value $400 answer Roman Catholicism became Italy's P.M. & a state in 2' value $800 answer Russell Crowe round Double Jeopardy! Show_number 4822 category TV GAME.